The Funko Pop "Grenade Damage" Joker is from Suicide Squad's third trailer that didn't make it into the movie. Reportedly, the scene took place at the end of Suicide Squad with Joker after the helicopter crash and a grenade in his hand. Joker calls for Harley Quinn, but she refuses and decides to stay with her new friends. Then Joker throws the grenade to cover his escape.
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If it's anything like last year's NYCC, it's a complete zoo to get these things. You need to first line up to get a wristband, and then line-up again to get the Pop. Towards the end of the con Funko did let people line up who don't have wristbands, but I'm guessing this Grenade Damaged Joker will go pretty quick.